This study is aimed at investigating the interactive effects of reaction parameters such as temperature (330–370 °C), total pressure (30–50 bar) and liquid hourly space velocity LHSV (1–3 h⁻¹) on the performance of hydrodesulfurization (HDS) activity. Experiments were performed based on the central composite rotatable design and analyzed using the response surface methodology (RSM). First, the equation model is used to predict HDS activity as a response. Second, the regression analysis of the HDS activity model is obtained from the output of this developed model. Finally, the RSM and canonical analysis is used to optimize this empirical regression model. R ² = 96.5 % showed that the RSM model fitted the observed data well with and is considered to be accurate and available for predicting HDS activity. The obtained equation for the canonical analysis with different signs of eigenvalues …

ABSTRACT

In order to capture the effect of joint progressive stiffness degradation with the hardening effect taken into account, the three parametric continuous model is adopted hereafter for the analytical formulation. The current paper is an extension of the previous work (Gizejowski et al. 2012) giving all the details of the developed model together with a calibration procedure for basic model parameters. Experimental data used was obtained from laboratory tests carried out at the Warsaw University of Technology for beam-to-column joints of different reinforcement ratio. The results of calibration exercise as well as the values of calibrated model parameters are given for practical application.

This study focuses on methylol functional benzoxazines as precursors to build a network structure utilizing both benzoxazine and resole chemistry. The first part is a review of systems that contain methylol groups which play a role on their crosslinking formation. The polymerization mechanism and properties of resoles will be highlighted as the most abundant polymers that are characterized by polymerization through condensation reaction of methylol group. In the second part, the effect of incorporating methylol group into benzoxazine monomers is studied. Differential scanning calorimetry (DSC) is used to study the effect of methylol group on the rate of polymerization. Kissinger and Ozawa methods using non-isothermal DSC at different heating rates show that methylol monomer exhibits lower average activation energy compared to the un-functionalized monomer. The effect of adding catalysts into the monomers is …

The characteristics of composite materials are of high importance to engineering applications; therefore the increasing use as a substitute for conventional materials, especially in the field of aircraft and space industries. It is a known fact that researchers use finite element programs for the design and analysis of composite structures, use of symmetrical conditions especially in complicated structures, in the modeling and analysis phase of the design, to reduce processing time, memory size required, and simplifying complicated calculations, as well as considering the response of composite structures to different loading conditions to be identical to that of metallic structures. Finite element methods are a popular method used to analyze composite laminate structures. The design of laminated composite structures includes phases that do not exist in the design of traditional metallic structures, for instance, the choice of possible material combinations is huge and the mechanical properties of a composite structure, which are anisotropic by nature, are created in the design phase with the choice of the appropriate fiber orientations and stacking sequence. The use of finite element programs (conventional analysis usually applied in the case of orthotropic materials) to analysis composite structures especially those manufactured using angle ply laminate techniques or a combination of cross and angle ply techniques, as well considering the loading response of the composite structure to be identical to that of structures made of traditional materials, has made the use of, and the results obtained by using such analysis techniques and conditions questionable. Hence, the main objective of this paper is to highlight and present the results obtained when analyzing and modeling symmetrical conditions as applied to commercial materials and that applied to composite laminates. A comparison case study is carried out using cross-ply and angle-ply laminates which concluded that, if the composition of laminate structure is pure cross-ply, the FEA is well suited for predicting the mechanical response of composite structure using principle of symmetry condition. On the other hand that is not the case for angle-ply or mixed-ply laminate structure.

The aim of this work was to establish the deformation behavior of two vanadium mic-roalloyed medium carbon steels with different contents of carbon and titanium by tensile testing at 77 K. Samples were reheated at 1250 C for 30 min and continuously cooled in still air. Beside acicular ferrite as the dominant morphology in both microstructures, the steel with lower content of carbon and negligible amount of titanium contains consi-derable fraction of grain boundary ferrite and pearlite. It was found that Ti-free steel exhibits a higher strain hardening rate and significantly lower elongation at 77 K than the fully acicular ferrite steel. The difference in tensile behavior at 77 K of the two steels has been associated with the influence of the pearlite, together with higher dislocation density of acicular ferrite.

Abstract: This paper presenting the effect of corrugation geometry on the crushing behavior, energy absorption, failure mechanism, and failure mode of woven roving glass fibre/epoxy laminated composite tubes subjected to lateral compression load. A comprehensive experimental program has been carried out on three geometrically different types of composite tubes: radial corrugated composite tubes, cylindrical composite tubes, and corrugated surrounded by cylindrical tubes. The three structures are made of woven roving glass fibre/epoxy 600 g/sqm. All specimens fabricated under the same conditions with a fixed number of layers equal to six.

Modeling of take-off and landing motion for a fixed wing (UAV) is necessary for developing an automatic take off and landing control system (ATOL). Automatic take off and landing system becomes an important system due to wide spread of unmanned aerial vehicles in different applications ranging from intelligence, surveillance, up to missile firing. Automatic take off and landing system reduces damage to an unmanned aerial vehicle and its payload that may be caused by human pilot errors. Furthermore, training human pilot to a sufficient level of skill and experience for takeoff and landing may take several years and significant cost. A human pilot also may impose additional restrictions for UAV operation especially at night time or dusty desert conditions. Although, ATOL adds complexity to the system, it reduces the long run cost and risk caused by takeoff and landing process, and makes UAV takeoff from different runways and at different atmospheric conditions. A mathematical model for takeoff is successfully developed for a small fixed wing UAV. A Matlab/Simulink simulation model is prepared for the ground roll phase, and some simulation results are also shown.

The aim of this work was to determine TTT diagram of medium carbon V-N micro-alloyed steel with emphasis on the

development of intragranular ferrite morphologies. The isothermal treatment was carried out at 350, 400, 450, 500, 550

and 600 οC. These treatments were interrupted at different times in order to analyze the evolution of the microstructure.

Metallographic evaluation was done using optical and scanning electron microscopy (SEM). The results show that at high

temperatures (≥ 500 ○C) polygonal intragranulary nucleated ferrite idiomorphs, combined with grain boundary ferrite and

pearlite were produced and followed by an incomplete transformation phenomenon. At intermediate temperatures (450, 500

○C) an interloced acicular ferrite (AF) microstructure is produced, and at low temperatures (400, 350 ○C) the sheave of

parallel acicular ferrite plates, similar to bainitic sheaves but intragranularly nucleated were observed. In addition to sheaf

type acicular ferrite, the grain boundary nucleated bainitic sheaves are observed.